But he never got to take a spot kick in the shootout that Croatia won 4-2 to move into the semi-finals.
Pre-tournament favourites Brazil must now wait at least another four years to win their sixth World Cup — their last dates back to 2002.
“I am psychologically destroyed. It is definitely the defeat which has hurt me the most, which left me paralysed for ten minutes after the match, after which I burst into tears without being able to stop,” Neymar said in an Instagram message.
“It is going to hurt for a very long time, unfortunately,” he added.
Neymar said immediately after Brazil crashed out that he might have played his last match for his country — but Pele urged him to “keep inspiring us.”
The 82-year-old said on Instagram he hoped the superstar forward would carry on playing, adding that goalscoring achievements were no match for the honour of representing Brazil.

England battle Norway as Argentina face Swiss in World Cup last eight
World Cup: Spain, France semi-final clash, final before the final – De la Fuente
African results justify World Cup slots increase amid criticism
Everyone expects Spain to beat us, says Belgium coach
Okoye backs France to win World Cup
Joshua, Fury opponents vow to ruin mega-fight plans
C’wealth Games: Olopade targets swimming, judo breakthrough
Teen girl dies celebrating France’s World Cup win
Balogun apologises to fans after US W’Cup exit
Eaglets suffer second defeat in China tourney
Alalshikh sets condition for Joshua, Fury Wembley fight
France urges calm during World Cup game against MoroccoFrance urges calm during World Cup game against Morocco
Rangers International going, going . . . (63,946 views)
Amaju Pinnick: A cat with nine lives (55,284 views)
Second Term: Amaju Pinnick, Other NFF Heavyweights Home to Roost •How Pinnick Broke the Jinx (53,193 views)
Current issues in Nigerian sports: Matters arising (52,802 views)
Sports Development: Zenith Bank on the zenith (52,687 views)
Missing $150,000 IAAF Grant: Solomon Dalung’s Hide and Seek game (52,555 views)
Gov. Abdullahi Ganduje’s solid footprints, commitment to sports development in Kano State (52,443 views)
NFF Presidency: Pinnick, Maigari, Ogunjobi, Okoye in Battle for Supremacy (51,963 views)
Olopade, BET9A wave of revolution in NNL (51,178 views)
Commonwealth Games 2018: Shame of Muhammadu Buhari, Solomon Dalung (49,646 views)
Ibrahimovic’s Man U exit: Whose decision is it? And in whose interest? (48,124 views)
John Mikel Obi: Segun Odegbami’s Outrageous Call! (47,515 views)