But he never got to take a spot kick in the shootout that Croatia won 4-2 to move into the semi-finals.
Pre-tournament favourites Brazil must now wait at least another four years to win their sixth World Cup — their last dates back to 2002.
“I am psychologically destroyed. It is definitely the defeat which has hurt me the most, which left me paralysed for ten minutes after the match, after which I burst into tears without being able to stop,” Neymar said in an Instagram message.
“It is going to hurt for a very long time, unfortunately,” he added.
Neymar said immediately after Brazil crashed out that he might have played his last match for his country — but Pele urged him to “keep inspiring us.”
The 82-year-old said on Instagram he hoped the superstar forward would carry on playing, adding that goalscoring achievements were no match for the honour of representing Brazil.

Eguavoen backs NPFL talents for Nigeria squad despite CHAN failure
He’s very strong, Simeone returns Osimhen praise
Joshua boxing return still uncertain
NBA star Bane eyes Nigeria switch
Palmer 'very, very happy' at Chelsea, says Rosenior
AFCON 2025: VAR recording discloses what referee said before Morocco's penalty miss against Senegal
AFCON 2025 highlights: World-class stadiums, VAR drama, record attendance
Oliseh slams Osimhen for costing Eagles’ AFCON trophy
3000 athletes, officials for Niger Delta Games in Edo
AFCON refs not up to standard – Henry
AFCON 2025: Akor Adams’ goal named among CAF’s top five
Joshua won’t want driver in jail – Uncle
Rangers International going, going . . . (63,494 views)
Amaju Pinnick: A cat with nine lives (54,787 views)
Second Term: Amaju Pinnick, Other NFF Heavyweights Home to Roost •How Pinnick Broke the Jinx (52,683 views)
Current issues in Nigerian sports: Matters arising (52,344 views)
Sports Development: Zenith Bank on the zenith (52,276 views)
Missing $150,000 IAAF Grant: Solomon Dalung’s Hide and Seek game (52,187 views)
Gov. Abdullahi Ganduje’s solid footprints, commitment to sports development in Kano State (52,053 views)
NFF Presidency: Pinnick, Maigari, Ogunjobi, Okoye in Battle for Supremacy (51,607 views)
Olopade, BET9A wave of revolution in NNL (50,786 views)
Commonwealth Games 2018: Shame of Muhammadu Buhari, Solomon Dalung (49,311 views)
Ibrahimovic’s Man U exit: Whose decision is it? And in whose interest? (47,703 views)
John Mikel Obi: Segun Odegbami’s Outrageous Call! (47,172 views)